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Experiments and Considerations Touching Colours

by Robert Boyle

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Experiment XLIV

It may (Pyrophilus) somewhat contribute towards the shewing how much some Colours depend upon the less or greater mixture, and (as it were,) Contemperation of the Light with shades, to observe, how that sometimes the number of Particles, of the same Colour, receiv’d into the Pores of a Liquor, or swiming up and down in it, do seem much to vary the Colour of it. I could here present you with particular instances to show, how in many (if not most) consistent Bodyes, if the Colour be not a Light one, as White, Yellow, or the like, the closeness of parts in the Pigments makes it look Blackish, though when it is display’d and laid on thinly, it will perhaps appear to be either Blew, or Green, or Red. But the Colours of consistent Pigments, not being those which the Preamble of this Experiment has lead you to expect Examples in, I shall take the instances I am now to give you, rather from Liquors than Dry Bodyes. If then you put a little fair Water into a cleer and slender Vial, (or rather into one of those pipes of Glass, which we shall by and by mention;) and let fall into it a few drops of a strong Decoction or Infusion of Cochineel, or (for want of that) of Brazil; you may see the tincted drops descend like little Clouds into the Liquor; through which, if, by shaking the Vial, you diffuse them, they will turn the water either of a Pinck Colour, or like that which is wont to be made by the washing of raw flesh in fair Water; by dropping a little more of the Decoction, you may heighten the Colour into a fine Red, almost like that which ennobles Rubies; by continuing the affusion, you may bring the Liquor to a kind of a Crimson, and afterwards to a Dark and Opacous Redness, somewhat like that of Clotted Blood. And in the passage of the Liquor from one of these Colours to the other, you may observe, if you consider it attentively, divers other less noted Colours belonging to Red, to which it is not easie to give Names; especially considering how much the proportion of the Decoction to the fair Water, and the strength of that Decoction, together with that of the trajected Light and other Circumstances, may vary the Phænomena of this Experiment. For the convenienter making whereof, we use instead of a Vial, any slender Pipe of Glass of about a foot or more in length, and about the thickness of a mans little finger; For, if leaving one end of this Pipe open, you Seal up the other Hermetically, (or at least stop it exquisitely with a Cork well fitted to it, and over-laid with hard Sealing Wax melted, and rubb’d upon it;) you shall have a Glass, wherein may be observ’d the Variations of the Colours of Liquors much better than in large Vials, and wherein Experiments of this Nature may be well made with very small quantities of Liquor. And if you please, you may in this Pipe produce variety of Colours in the various parts of the Liquor, and keep them swimming upon one another unmix’d for a good while. And some have marveil’d to see, what variety of Colours we have sometimes (but I confess rather by chance than skill) produc’d in those Glasses, by the bare infusion of Brazil, variously diluted with fair Water, and alter’d by the Infusion of several Chymical Spirits and other Saline Liquors devoid themselves of Colour, and when the whole Liquor is reduc’d to an Uniform degree of Colour, I have taken pleasure to make that very Liquor seem to be of Colours gradually differing, by filling with it Glasses of a Conical figure, (whether the Glass have its basis in the ordinary position, or turn’d upwards.) And yet you need not Glasses of an extraordinary shape to see an instance of what the vari’d mixture of Light and Shadow can do in the diversifying of the Colour. For if you take but a large round Vial, with a somewhat long and slender Neck, and filling it with our Red Infusion of Brazil, hold it against the Light, you will discern a notable Disparity betwixt the Colour of that part of the Liquor which is in the Body of the Vial, and that which is more pervious to the Light in the Neck. Nay, I remember, that I once had a Glass and a Blew Liquor (consisting chiefly (or only, if my memory deceive me not,) of a certain Solution of Verdigrease) so fitted for my purpose, that though in other Glasses the Experiment would not succeed, yet when that particular Glass was fill’d with that Solution, in the Body of the Vial it appear’d of a Lovely Blew, and in the neck, (where the Light did more dilute the Colour,) of a manifest Green; and though I suspected there might be some latent Yellowness in the substance of the neck of the Glass, which might with the Blew compose that Green, yet was I not satisfi’d my self with my Conjecture, but the thing seem’d odd to me, as well as to divers curious persons to whom it was shown. And I lately had a Broad piece of Glass, which being look’d on against the Light seem’d clear enough, and held from the Light appear’d very lightly discolour’d, and yet it was a piece knock’d off from a great lump of Glass, to which if we rejoyn’d it, where it had been broken off, the whole Mass was as green as Grass. And I have several times us’d Bottles and stopples that were both made (as those, I had them from assur’d me) of the very same Metall, and yet whilst the bottle appear’d but inclining towards a Green, the Stopple (by reason of its great thickness) was of so deep a Colour that you would hardly believe they could possibly be made of the same materials. But to satisfie some Ingenious Men, on another occasion, I provided my self of a flat Glass (which I yet have by me,) with which if I look against the Light with the Broad side obverted to the Eye, it appeares like a good ordinary window Glass; but if I turn the Edge of it to my Eye, and place my Eye in a convenient posture in reference to the Light, it may contend for deepness of Colour with an Emerald. And this Greeness puts me in mind of a certain thickish, but not consistent Pigment I have sometimes made, and can show you when you please, which being dropp’d on a piece of White Paper appears, where any quantity of it is fallen, of a somewhat Crimson Colour, but being with ones finger spread thinly on the Paper does presently exhibit a fair Green, which seems to proceed only from its disclosing its Colour upon the Extenuation of its Depth into Superficies, if the change be not somewhat help’d by the Colours degenerating upon one or other of the Accounts formerly mention’d. Let me add, that having made divers Tryals with that Blew substance, which in Painters shops is call’d Litmase, we have sometimes taken Pleasure to observe, that being dissolv’d in a due proportion of fair Water, the Solution either oppos’d to the Light, or dropp’d upon White paper, did appear of a deep Colour betwixt Crimson and Purple; and yet that being spread very thin on the Paper and suffer’d to dry on there, the Paper was wont to appear Stain’d of a Fine Blew. And to satisfie my selfe, that the diversity came not from the Paper, which one might suspect capable of inbibing the Liquor, and altering the Colour, I made the Tryal upon a flat piece of purely White Glass’d Earth, (which I sometimes make use of about Experiments of Colours) with an Event not unlike the former.

And now I speak of Litmass, I will add, that having this very day taken a piece of it, that I had kept by me these several years, to make Tryals about Colours, and having let fall a few drops of the strong Infusion of it in fair water, into a fine Crystal Glass, shap’d like an inverted Cone, and almost full of fair Water, I had now (as formerly) the pleasure to see, and to show others, how these few tincted drops variously dispersing themselves through the Limpid Water, exhibited divers Colours, or varieties of Purple and Crimson. And when the Corpuscles of the Pigment seem’d to have equally diffus’d themselves through the whole Liquor, I then by putting two or three drops of Spirit of Salt, first made an odd change in the Colour of the Liquor, as well as a visible commotion among its small parts, and in a short time chang’d it wholly into a very Glorious Yellow, like that of a Topaz. After which if I let fall a few drops of the strong and heavy Solution of Pot-ashes, whose weight would quickly carry it to the sharp bottome of the Glass, there would soon appear four very pleasant and distinct Colours; Namely, a Bright, but Dilute Colour at the picked bottome of the Glass; a Purple, a little higher; a deep and glorious Crimson, (which Crimson seem’d to terminate the operation of the Salt upward) in the confines betwixt the Purple and the Yellow; and an Excellent Yellow, the same that before enobled the whole Liquor, reaching from thence to the top of the Glass. And if I pleas’d to pour very gently a little Spirit of Sal Armoniack, upon the upper part of this Yellow, there would also be a Purple or a Crimson, or both, generated there, so that the unalter’d part of the Yellow Liquor appear’d intercepted betwixt the two Neighbouring Colours.

My scope in this 3d. Experiment (Pyrophilus) is manifold, as first to invite you to be wary in judging of the Colour of Liquors in such Glasses as are therein recommended to you, and consequently as much, if not more, when you imploy other Glasses. Secondly, That you may not think it strange, that I often content my self to rub upon a piece of White paper, the Juice of Bodies I would examine, since not onely I could not easily procure a sufficient Quantity of the juices of divers of them; but in several Cases the Tryals of the quantities of such Juices in Glasses would make us more lyable to mistakes, than the way that in those cases I have made use of. Thirdly, I hope you will by these and divers other particulars deliver’d in this Treatise, be easily induc’d to think that I may have set down many Phænomena very faithfully, and just as they appear’d to me, and yet by reason of some unheeded circumstance in the conditions of the matter, and in the degree of Light, or the manner of trying the Experiment, you may find some things to vary from the Relations I make of them. Lastly, I design’d to give you an opportunity to free your self from the amazement which possesses most Men, at the Tricks of those Mountebancks that are commonly call’d Water-drinkers. For though not only the vulgar, but ev’n many persons that are far above that Rank, have so much admir’d to see, a man after having drunk a great deal of fair water, to spurt it out again in the form of Claret Wine, Sack, and Milk, that they have suspected the intervening of Magick, or some forbidden means to effect what they conceived above the power of Art; yet having once by chance had occasion to oblige a Wanderer that made profession of that and other Jugling Tricks, I was easily confirm’d by his Ingenious confession to me, That this so much Admir’d Art, indeed consisted rather in a few Tricks, than in any great Skill, in altering the Nature and Colours of things. And I am easy to be perswaded; that there may be a great deal of Truth in a little Pamphlet Printed divers years ago in English, wherein the Author undertakes to discover, and that (if I mistake not) by the confession of some of the Complices themselves, That a famous Water-drinker then much Admir’d in England, perform’d his pretended Transmutations of Liquors by the help of two or three inconsiderable preparations and mixtures of not unobvious Liquors, and chiefly of an Infusion of Brazil variously diluted and made Pale or Yellowish, (and otherwise alter’d) with Vinegar, the rest of their work being perform’d by the shape of the Glasses, by Craft and Legerdemane. And for my part, that which I marvel at in this business, is, the Drinkers being able to take down so much Water, and spout it out with that violence; though Custome and a Vomit seasonably taken before hand, may in some of them much facilitate the work. But as for the changes made in the Liquors, they were but few and slight in comparison of those, that the being conversant in Chymical Experiments, and dextrous in applying them to the Transmuting of Colours, may easily enough enable a man to make, as ev’n what has been newly deliver’d in this, and the foregoing Experiment; especially if we add to it the things contained in the XX, the XXXIX and the XL. Experiments, may perhaps have already perswaded You.

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