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Experiments and Considerations Touching Colours

by Robert Boyle

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Experiment XLII

That the Colour (Pyrophilus) of a Body may be chang’d by a Liquor which of it self is of no Colour, provided it be Saline, we have already manifested by a multitude of instances. Nor doth it seem so strange, because Saline Particles swimming up and down in Liquors, have been by many observ’d to be very operative in the Production and change of Colours. But divers of our Friends that are not acquainted with Chymical Operations have thought it very strange that a White Body, and a Dry one too, should immediately acquire a rich new Colour upon the bare affusion of Spring-Water destitute as well of adventitious Salt as of Tincture. And yet (Pyrophilus) the way of producing such a change of Colours may be easily enough lighted on by those that are conversant in the Solutions of Mercury. For we have try’d, that though by Evaporating a Solution of Quick-Silver in Aqua-fortis, and abstracting the Liquor till the remaining matter began to be well, but not too strongly dryed, fair Water pour’d on the remaining Calx made it but somewhat Yellowish; yet when we took good Quick-Silver, and three or four times its weight of Oyl of Vitriol, in case we in a Glass Retort plac’d in Sand drew off the Saline Menstruum from the Metalline Liquor, till there remain’d a dry Calx at the bottome, though this Precipitate were a Snow White Body, yet upon pouring on it a large quantity of fair Water, we did almost in a moment perceive it to pass from a Milky Colour to one of the loveliest Light Yellows that ever we had beheld. Nor is the Turbith Mineral, that Chymists extol for its power to Salivate, and for other vertues, of a Colour much inferiour to this, though it be often made with a differing proportion of the Ingredients, a more troublesome way. For Beguinus,22 who calls it Mercurius præcipitatus optimus, takes to one part of Quick-Silver, but two of Liquor, and that is Rectifi’d Oyl of Sulphur, which is (in England at least) far more scarce and dear than Oyl of Vitriol; he also requires a previous Digestion, two or three Cohobations, and frequent Ablutions with hot Distill’d Water, with other prescriptions, which though they may conduce to the Goodness of the Medicine, which is that he aims at, are troublesome, and, our Tryals have inform’d you unneccessary to the obtaining the Lemmon Colour which he regards not. But though we have very rarely seen either in Painters Shops, or elsewhere a finer Yellow than that which we have divers times this way produc’d (which is the more considerable, because durable and pleasant Yellows are very hard to be met with, as may appear by the great use which Painters are for its Colours sake fain to make of that pernicious and heavy Mineral, Orpiment) yet I fear our Yellow is too costly, to be like to be imploy’d by Painters, unless about Choice pieces of Work, nor do I know how well it will agree with every Pigment, especially, wich Oyl’d Colours. And whether this Experiment, though it have seem’d somewhat strange to most we have shown it to, be really of another Nature than those wherein Saline Liquors are imploy’d, may, as we formerly also hinted, be so plausibly doubted, that whether the Water pour’d on the Calx, do barely by imbibing some of its Saline parts alter its Colour by altering its Texture, or whether by dissolving the Concoagulated Salts, it does become a Saline Menstruum, and, as such, work upon the Mercury, I freely leave to you (Pyrophilus) to consider. And that I may give you some Assistance in your Enquiry, I will not only tell you, that I have several times with fair Water wash’d from this Calx, good store of strongly tasted Corpuscles, which by the abstraction of the Menstruum, I could reduce into Salt; but I will also subjoyn an Experiment, which I devis’d, to shew among other things, how much a real and permanent Colour may be as it were drawn forth by a Liquor that has neither Colour, nor so much as Saline or other Active parts, provided it can but bring the parts of the Body it imbibes to convene into clusters dispos’d after the manner requisite to the exhibiting of the emergent Colour. The Experiment was this.

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