Experiment XLIX
Meeting the other day, Pyrophilus, in an Italian book, that treats of other matters, with a way of preparing what the Author calls a Lacca of Vegetables, by which the Italians mean a kind of Extract fit for Painting, like that rich Lacca in Engliſh commonly call’d Lake, which is imploy’d by Painters as a glorious Red. And finding the Experiment not to be inconſiderable, and very defectively ſet down, it will not be amiſs to acquaint you with what ſome Tryals have inform’d us, in reference to this Experiment, which both by our Italian Author, and by divers of his Countrymen, is look’d upon as no trifling Secret.
Take then the root call’d in Latin Curcuma, and in Engliſh Turmerick, (which I made uſe of, becauſe it was then at hand, and is among Vegetables fit for that purpoſe one of the moſt eaſieſt to be had) and when it is beaten, put what Quantity of it you pleaſe into fair Water, adding to every pound of Water about a ſpoonfull or better of as ſtrong a Lixivium or Solution of Potaſhes as you can well make, clarifying it by Filtration before you put it to the Decocting water. Let theſe things boyl, or rather ſimper over a ſoft Fire in a clean glaz’d Earthen Veſſel, till you find by the Immerſion of a ſheet of White Paper (or by ſome other way of Tryal) that the Liquor is ſufficiently impregnated with the Golden Tincture of the Turmerick, then take the Decoction off the Fire, and Filter or Strain it that it may be clean, and leiſurely dropping into it a ſtrong Solution of Roch Allum, you ſhall find the Decoction as it were curdl’d, and the tincted part of it either to emerge, to ſubſide, or to ſwim up and down, like little Yellow flakes; and if you pour this mixture into a Tunnel lin’d with Cap Paper, the Liquor that Filtred formerly ſo Yellow, will now paſs clean thorow the Filtre, leaving its tincted, and as it were curdled parts in the Filtre, upon which fair Water muſt be ſo often pour’d, till you have Dulcifi’d the matter therein contain’d, the ſign of which Dulcification is (you know) when the Water that has paſs’d through it, comes from it as taſteleſs as it was pour’d on it. And if without Filtration you would gather together the flakes of this Vegetable Lake, you muſt pour a great Quantity of fair Water upon the Decoction after the affuſion of the Alluminous Solution, and you ſhall find the Liquor to grow clearer, and the Lake to ſettle together at the bottom, or emerge to the top of the Water, though ſometimes having not pour’d out a ſufficient Quantity of fair Water, we have obſerv’d the Lake partly to ſubſide, and partly to emerge, leaving all the middle of the Liquor clear. But to make this Lake fit for uſe, it muſt by repeated affuſions of freſh Water, be Dulcifi’d from the adhering Salts, as well as that ſeparated by Filtration, and be ſpread and ſuffer’d to dry leiſurely upon pieces of Cloth, with Brown Paper, or Chalk, or Bricks under them to imbibe the Moiſture25.
Annotation I.
Whereas it is preſum’d that the Magiſtery of Vegetables obtain’d this way conſiſts but of the more Soluble and Coloured parts of the Plants that afford it, I muſt take the liberty to Queſtion the ſuppoſition. And for my ſo doing, I ſhall give you this account.
According to the Notions (ſuch as they were) that I had concerning Salts; Allom, though to ſenſe a Homogeneous Body, ought not to be reckon’d among true Salts, but to be it ſelf look’d upon as a kind of Magiſtery, in regard that as Native Vitriol (for ſuch I have had) contains both a Saline ſubſtance and a Metall, whether Copper, or Iron, corroded by it, and aſſociated with it; ſo Allom which may be of ſo near a kin to Vitriol, that in ſome places of England (as we are aſſur’d by good Authority the ſame ſtone will ſometimes afford both) ſeems manifeſtly to contain a peculiar kind of Acid Spirit, generated in the Bowels of the Earth, and ſome kind of ſtony matter diſſolv’d by it. And though in making our ordinary Allom, the Workmen uſe the Aſhes of a Sea Weed (vulgarly call’d Kelp) and Urine: yet thoſe that ſhould know, inform us, that, here in England, there is beſides the factitious Allom, Allom made by Nature Without the help of thoſe Additaments. Now (Pyrophilus) when I conſider’d this compoſition of Allom, and that Alcalizate Salts are wont to Præcipitate what acid Salts have diſſolv’d, I could not but be prone to ſuſpect that the Curdled Matter, which is call’d the Magiſtery of Vegetables, may have in it no inconſiderable proportion of a ſtony ſubſtance Præcipitated out of the Allom by the Lixivium, wherein the Vegetable had been decocted, and to ſhew you, that there is no neceſſity, that all the curdl’d ſubſtance muſt belong to the Vegetable, I ſhall add, that I took a ſtrong Solution of Allom, and having Filtred it, by pouring in a convenient Quantity of a ſtrong Solution of Potaſhes, I preſently, as I expected, turn’d the mixture into a kind of white Curds, which being put to Filtre, the Paper retain’d a ſtony Calx, copious enough, very White, and which ſeem’d to be of a Mineral Nature, both by ſome other ſignes, and this, that little Bits of it being put upon a live Coal, which was Gently Blown whilſt they were on it, they did neither melt nor fly away, and you may keep a Quantity of this White ſubſtance for a good while, (nay for ought I can gueſs for a very long one) in a red hot Crucible without loſing or ſpoiling it; nor did hot Water wherein I purpoſely kept another parcel of ſuch Calx, ſeem to do any more than waſh away the looſer adhering Salts from the ſtony ſubſtance, which therefore ſeem’d unlikely to be ſeparable by ablutions (though reiterated) from the Præcipitated parts of the Vegetable, whoſe Lake is intended. And to ſhew you, that there is likewiſe in Allom a Body, with which the fix’d Salt of the Alcalizate Solution will concoagulate into a Saline Subſtance differing from either of them, I ſhall add, that I have taken pleaſure to recover out of the ſlowly exhal’d Liquor, that paſs’d through the filtre, and left the foremention’d Calx behind, a Body that at leaſt ſeem’d a Salt very pretty to look on, as being very White, and conſiſting of an innumerable company of exceeding ſlender, and ſhining Particles, which would in part eaſily melt at the flame of a Candle, and in part flye away with ſome little noiſe. But of this ſubſtance, and its odd Qualities more perhaps elſewhere; for now I ſhall only take notice to you, that I have likewiſe with Urinous Salts, ſuch as the Spirit of Sal Armoniack, as well as with the Spirit of Urine it ſelf, Nay, (if I much miſtake not) ev’n with Stale Urine undiſtil’d, eaſily Precipitated ſuch a White Calx as I was formerly ſpeaking of, out of a Limpid Solution of Allom, ſo that there is need of Circumſpection in judging of the Natures of Liquors by Precipitations wherein Allom intervenes, elſe we may ſometimes miſtakingly imagine that to be Precipitated out of a Liquor by Allom, which is rather Precipitated out of Allom by the Liquor: And this puts me in mind to tell you, that ’tis not unpleaſant to behold how quickly the Solution of Allom (or injected lumps of Allom) do’s occaſion the ſevering of the colour’d parts of the Decoction from the Liquor that ſeem’d to have ſo perfectly imbib’d them.
Annot. II.
The above mention’d way of making Lakes we have tryed not only with Turmerick, but alſo with Madder, which yielded us a Red Lake; and with Rue, which afforded us an extract, of (almoſt if not altogether) the ſame Colour with that of the leaves.
But in regard that ’tis Principally the Alcalizate Salt of the Pot-aſhes, which enables the water to Extract ſo powerfully the Tincture of the Decocted Vegetables, I fear that our Author may be miſtaken by ſuppoſing that the Decoction will alwayes be of the very ſame Colour with the Vegetable it is made off. For Lixiviate Salts, to which Pot-aſhes eminently belong, though by peircing and opening the Bodies of Vegetables, they prepare and diſpoſe them to part readily with their Tincture, yet ſome Tinctures they do not only draw out, but likewiſe alter them, as may be eaſily made appear by many of the Experiments already ſet down in this Treatiſe, and though Allom being of an Acid Nature, its Solutions may in ſome Caſes deſtroy the Adventitious Colours produc’d by the Alcaly, and reſtore the former: yet beſides that Allom is not, as I have lately ſhown, a meer Acid Salt, but a mixt Body, and beſides, that its operations are languid in compariſon of the activity of Salts freed by Diſtillation, or by Incineration and Diſſolution, from the moſt of their Earthy parts, we have ſeen already Examples, that in divers Caſes an Acid Salt will not reſtore a Vegetable ſubſtance to the Colour of which an Alcalizate one had depriv’d it, but makes it aſſume a third very differing from both, as we formerly told you, that if Syrrup of Violets were by an Alcaly turn’d Green, (which Colour, as I have try’d, may be the ſame way produc’d in the Violet-leaves themſelves without any Relation to a Syrrup) an Acid Salt would not make it Blew again, but Red. And though I have by this way of making Lakes, made Magiſteries (for ſuch they ſeem to be) of Brazil, and as I remember of Cochinele it ſelf, and of other things, Red, Yellow or Green which Lakes were enobled with a Rich Colour, and others had no bad one; yet in ſome the colour of the Lake ſeem’d rather inferiour than otherwiſe to that of the Plant, and in others it ſeem’d both very differing, and much worſe; but Writing this in a time and place where I cannot provide my ſelf of Flowres and other Vegetables to proſecute ſuch Tryals in a competent variety of Subjects, I am content not to be poſitive in delivering a judgment of this way of Lakes, till Experience, or You, Pyrophilus, ſhall have afforded me a fuller and more particular Information.
Annotation III.
And on this occaſion (Pyrophilus) I muſt here (having forgot to do it ſooner) advertiſe you once for all, that having written ſeveral of the foregoing Experiments, not only in haſte but at ſeaſons of the year, and in places wherein I could not furniſh my ſelf with ſuch Inſtruments, and ſuch a variety of Materials, as the deſign of giving you an Introduction into the Hiſtory of Colours requir’d, it can ſcarce be otherwiſe but that divers of the Experiments, that I have ſet down, may afford you ſome matter of new Tryals, if you think fit to ſupply the deficiencies of ſome of them (eſpecially the freſhly mention’d about Lakes, and thoſe that concern Emphatical Colours) which deficiencies for want of being befriended with accommodations I could better diſcern than avoid.
Annotation IV.
The uſe of Allom is very great as well as familiar in the Dyers Trade, and I have not been ill pleas’d with the uſe I have been able to make of it in preparing other pigments than thoſe they imploy with Vegetable Juices. But the Lucriferous practiſes of Dyers and other Tradeſmen, I do, for Reaſons that you may know when you pleaſe, purpoſely forbear in this Eſſay, though not ſtrictly from pointing at, yet from making it a part of my preſent work explicitly and circumſtantially to deliver, eſpecially ſince I now find (though late and not without ſome Bluſhes at my prolixity) that what I intended but for a ſhort Eſſay, is already ſwell’d into almoſt a Volume.