Experiment XVII
The emergency, Pyrophilus, of Colours upon the Coalition of the Particles of ſuch Bodies as were neither of them of the Colour of that Mixture whereof they are the Ingredients, is very well worth our attentive Obſervation, as being of good uſe both Speculative and Practical; For much of the Mechanical uſe of Colours among Painters and Dyers, doth depend upon the Knowledge of what Colours may be produc’d by the Mixtures of Pigments ſo and ſo Colour’d. And (as we lately intimated) ’tis of advantage to the contemplative Naturaliſt, to know how many and which Colours are Primitive (if I may ſo call them) and Simple, becauſe it both eaſes his Labour by confining his moſt ſollicitous Enquiry to a ſmall Number of Colours upon which the reſt depend, and aſſiſts him to judge of the nature of particular compounded Colours, by ſhewing him from the Mixture of what more Simple ones, and of what Proportions of them to one another, the particular Colour to be conſider’d does reſult. But becauſe to inſiſt on the Proportions, the Manner and the Effects of ſuch Mixtures would oblige me to conſider a greater part of the Painters Art and Dyers Trade, than I am well acquainted with, I confin’d my ſelf to make Trial of ſeveral ways to produce Green, by the compoſition of Blew and Yellow. And ſhall in this place both Recapitulate moſt of the things I have Diſperſedly deliver’d already concerning that Subject, and Recruit them.
And firſt, whereas Painters (as I noted above) are wont to make Green by tempering Blew and Yellow, both of them made into a ſoft Conſiſtence, with either Water or Oyl, or ſome Liquor of Kin to one of thoſe two, according as the Picture is to be Drawn with thoſe they call water Colours, or thoſe they term Oyl Colours, I found that by chooſing fit Ingredients, and mixing them in the form of Dry Powders, I could do, what I could not if the Ingredients were temper’d up with a Liquor; But the Blew and Yellow Powders muſt not only be finely Ground, but ſuch as that the Corpuſcles of the one may not be too unequal to thoſe of the other, leſt by their Diſproportionate Minuteneſs the Smaller cover and hide the Greater. We us’d with good ſucceſs a ſlight Mixture of the fine Powder of Biſe, with that of Orpiment, or that of good Yellow Oker, I ſay a ſlight Mixture, becauſe we found that an exquiſite Mixture did not do ſo well, but by lightly mingling the two Pigments in ſeveral little Parcels, thoſe of them in which the Proportion and Manner of Mixture was more Lucky, afforded us a good Green.
2. We alſo learn’d in the Dye-houſes, that Cloth being Dy’d Blew with Woad, is afterwards by the Yellow Decoction of Luteola or Woud-wax or Wood-wax Dy’d into a Green Colour.
3. You may alſo remember what we above Related, where we intimated, that having in a Darkn’d Room taken two Bodies, a Blew and a Yellow, and caſt the Light Reflected from the one upon the other, we likewiſe obtain’d a Green.
4. And you may remember, that we obſerv’d a Green to be produc’d, when in the ſame Darkn’d Room we look’d at the Hole at which alone the Light enter’d, through the Green and Yellow parts of a ſheet of Marbl’d Paper laid over one another.
5. We found too, that the Beams of the Sun being trajected through two pieces of Glaſs, the one Blew and the other Yellow, laid over one another, did upon a ſheet of White paper on which they were made to fall, exhibit a lovely Green.
6. I hope alſo, that you have not already forgot, what was ſo lately deliver’d, concerning the compoſition of a Green, with a Blew and Yellow; of which moſt Authors would call the one a Real, and the other an Emphatical.
7. And I preſume, you may have yet freſh in your memory, what the fourteenth Experiment informs you, concerning the exhibiting of a Green, by the help of a Blew and Yellow, that were both of them Emphatical.
8. Wherefore we will proceed to take notice, that we alſo devis’d a way of trying whether or no Metalline Solutions though one of them at leaſt had its Colour Adventitious, by the mixture of the Menstruum employ’d to diſſolve it, might not be made to compound a Green after the manner of other Bodies. And though this ſeem’d not eaſie to be perform’d by reaſon of the Difficulty of finding Metalline Solutions of the Colour requiſite, that would mix without Præcipitating each other; yet after a while having conſider’d the matter, the firſt Tryal afforded me the following Experiment. I took a High Yellow Solution of good Gold in Aqua-Regis, (made of Aqua-fortis, and as I remember half its weight of Spirit of Salt) To this I put a due Proportion of a deep and lovely Blew Solution of Crude Copper, (which I have elſewhere taught to be readily Diſſoluble in ſtrong Spirit of Urine) and theſe two Liquors though at firſt they ſeem’d a little to Curdle one another, yet being throughly mingl’d by Shaking, they preſently, as had been Conjectur’d, united into a Tranſparent Green Liquor, which continu’d ſo for divers days that I kept it in a ſmall Glaſs wherein ’twas made, only letting fall a little Blackiſh Powder to the Bottom. The other Phænomena of this Experiment belong not to this place, where it may ſuffice to take notice of the Production of a Green, and that the Experiment was more than once repeated with Succeſs.
9. And laſtly, to try whether this way of compounding Colours would hold ev’n in Ingredients actually melted by the Violence of the Fire, provided their Texture were capable of ſafely induring Fuſion, we caus’d ſome Blew and Yellow Ammel to be long and well wrought together in the Flame of a Lamp, which being Strongly and Inceſſantly blown on them kept them in ſome degree of Fuſion, and at length (for the Experiment requires ſome Patience as well as Skil) we obtain’d the expected Ammel of a Green Colour.
I know not, Pyrophilus, whether it be worth while to acquaint you with the ways that came into my Thoughts, whereby in ſome meaſure to explicate the firſt of the mention’d ways of making a Green; for I have ſometimes Conjectur’d, that the mixture of the Biſe and the Orpiment produc’d a Green by ſo altering the Superficial Aſperity, which each of thoſe Ingredients had apart, that the Light Incident on the mixture was Reflected with differing Shades, as to Quantity, or Order, or both, from thoſe of either of the Ingredients, and ſuch as the Light is wont to be Modify’d with, when it Reflects from Graſs, or Leaves, or ſome of thoſe other Bodies that we are wont to call Green. And ſometimes too I have doubted, whether the produced Green might not be partly at leaſt deriv’d from this, That the Beams that Rebound from the Corpuſcles of the Orpiment, giving one kind of ſtroak upon the Retina, whoſe Perception we call Yellow, and the Beams Reflected from the Corpuſcles of the Biſe, giving another ſtroak upon the ſame Retina, like to Objects that are Blew, the Contiguity and Minuteneſs of theſe Corpuſcles may make the Appulſe of the Reflected Light fall upon the Retina within ſo narrow a Compaſs, that the part they Beat upon being but as it were a Phyſical point, they may give a Compounded ſtroak, which may conſequently exhibit a Compounded and new Kind of Senſation, as we ſee that two Strings of a Muſical Inſtrument being ſtruck together, making two Noiſes that arrive at the Ear at the ſame time as to Senſe, yield a Sound differing from either of them, and as it were Compounded of both; Inſomuch that if they be Diſcordantly ton’d, though each of them ſtruck apart would yield a Pleaſing Sound, yet being ſtruck together they make but a Harſh and troubleſome Noiſe. But this not being ſo fit a place to proſecute Speculations, I ſhall not inſiſt, neither upon theſe Conjectures nor any others, which the Experiment we have been mentioning may have ſuggeſted to me. And I ſhall leave it to you, Pyrophilus, to derive what Inſtruction you can from comparing together the Various ways whereby a Yellow and a Blew can be made to Compound a Green. That which I now pretend to, being only to ſhew that the firſt of thoſe mention’d ways, (not to take at preſent notice of the reſt) does far better agree with our Conjectures about Colours, than either with the Doctrine of the Schools, or with that of the Chymiſts, both which ſeem to be very much Disfavour’d by it.
For firſt, ſince in the Mixture of the two mention’d Powders I could by the help of a very excellent Microſcope (for ordinary ones will ſcarce ſerve the turn) diſcover that which ſeem’d to the naked Eye a Green Body, to be but a heap of Diſtinct, though very ſmall Grains of Yellow Orpiment and Blew Biſe confuſedly enough Blended together, it appears that the Colour’d Corpuſcles of either kind did each retain its own Nature and Colour; By which it may be gueſs’d, what meer Tranſpoſition and Juxtapoſition of Minute and Singly unchang’d Particles of Matter can do to produce a new Colour; For that this Local Motion and new Diſpoſition of the ſmall parts of the Orpiment did Intervene is much more manifeſt than it is eaſie to Explicate how they ſhould produce this new Green otherwiſe than by the new Manner of their being put together, and conſequently by their new Diſpoſition to Modifie the Incident Light by Reflecting it otherwiſe than they did before they were Mingl’d together.
Secondly, The Green thus made being (if I may ſo ſpeak) Mechanically produc’d, there is no pretence to derive it from I know not what incomprehenſible Subſtantial Form, from which yet many would have us believe that Colours muſt flow; Nor does this Green, though a Real and Permanent, not a Phantaſtical and Vanid Colour, ſeem to be ſuch an Inherent Quality as they would have it, ſince not only each part of the Mixture remains unalter’d in Colour, and conſequently of a differing Colour from the Heap they Compoſe, but if the Eye be aſſiſted by a Microſcope to diſcern things better and more diſtinctly than before it could, it ſees not a Green Body, but a Heap of Blew and Yellow Corpuſcles.
And in the third place, I demand what either Sulphur, or Salt, or Mercury has to do in the Production of this Green; For neither the Biſe nor the Orpiment were indu’d with that Colour before, and the bare Juxtapoſition of the Corpuſcles of the two Powders that work not upon each other, but might if we had convenient Inſtruments be ſeparated, unalter’d, cannot with any probability be imagin’d either to Increaſe or Diminiſh any of the three Hypoſtatical Principles, (to which of them ſoever the Chymiſts are pleas’d to aſcribe Colours) nor does there here Intervene ſo much as Heat to afford them any colour to pretend, that at leaſt there is made an Extraverſion (as the Helmontians ſpeak) of the Sulphur or of any of the two other ſuppoſed Principles; But upon this Experiment we have already Reflected enough, if not more than enough for once.