Experiment XII
The way, Pyrophilus, of producing Whiteness by Chymical Præcipitations is very well worth our observing, for thereby Bodyes of very Differing Colours as well as Natures, though dissolv’d in Several Liquors, are all brought into Calces or Powders that are White. Thus we find that not only Crabs-eyes, that are of themselves White, and Pearls that are almost so, but Coral and Minium that are Red, being dissolv’d in Spirit of Vinegar, may be uniformly Præcipitated by Oyl of Tartar into White Powders. Thus Silver and Tin separately dissolv’d in Aqua Fortis, will the one Præcipitate it self, and the other be Præcipitated by common Salt-water into a White Calx, and so will Crude Lead and Quicksilver first dissolv’d likewise in Aqua Fortis. The like Calx will be afforded as I have try’d by a Solution of that shining Mineral Tinglass dissolv’d in Aqua Fortis, and Præcipitated out of it; and divers of these Calces may be made at least as Fair and White, if not better Colour’d, if instead of Oyl of Tartar they were Præcipitated with Oyl of Vitriol, or with another Liquor I could Name. Nay, that Black Mineral Antimony it self, being reduc’d by and with the Salts that concurr to the Composition of common Sublimate, into that Cleer though Unctuous Liquor that Chymists commonly call Rectifi’d Butter of Antimony, will by the bare affusion of store of Fair Water be struck down into that Snow-white Powder, which when the adhering Saltness is well wash’d off, Chymists are pleas’d to call Mercurius Vitæ, though the like Powder may be made of Antimony, without the addition of any Mercury at all. And this Lactescence if I may so call it, does also commonly ensue when Spirit of Wine, being Impregnated with those parts of Gums or other Vegetable Concretions, that are suppos’d to abound with Sulphureous Corpuscles, fair Water is suddenly pour’d upon the Tincture or Solution. And I remember that very lately I did, for Tryal sake, on a Tincture of Benjamin drawn with Spirit of Wine, and brought to be as Red as Blood, pour some fair Water, which presently mingling with the Liquor, immediately turn’d the whole Mixture White. But if such Seeming Milks be suffer’d to stand unstirr’d for a convenient while, they are wont to let fall to the bottome a Resinous Substance, which the Spirit of Wine Diluted and Weakned by the Water pour’d into it, was unable to support any longer. And something of Kin to this change of Colour in Vegetables is that, which Chymists are wont to observe upon the pouring of Acid Spirits upon the Red Solution of Sulphur, dissolv’d in an Infusion of Pot-ashes, or in some other sharp Lixivium, the Præcipitated Sulphur before it subsides, immediately turning the Red Liquor into a White one. And other Examples might be added of this way of producing Whiteness in Bodyes by Præcipitating them out of the Liquors wherein they have been Dissolv’d; but I think it may be more usefull to admonish you, Pyrophilus, that this observation admits of Restrictions, and is not so Universal, as by this time perhaps you have begun to think it; For though most Præcipitated Bodyes are White, yet I know some that are not; For Gold Dissolv’d in Aqua Regis, whether you Præcipitate it with Oyl of Tartar, or with Spirit of Sal Armoniack, will not afford a White but a Yellow Calx. Mercury also though reduc’d into Sublimate, and Præcipitated with Liquors abounding with Volatile Salts, as the Spirits drawn from Urine, Harts-horn, and other Animal substances, yet will afford, as we Noted in our first Experiment about Whiteness and Blackness, a White Præcipitate, yet with some Solutions hereafter to be mentioned, it will let fall an Orange-Tawny Powder. And so will Crude Antimony, if, being dissolv’d in a strong Lye, you pour (as farr as I remember) any Acid Liquor upon the Solution newly Filtrated, whilst it is yet Warm. And if upon the Filtrated Solution of Vitriol, you pour a Solution of one of these fix’d Salts, there will subside a Copious substance, very farr from having any Whiteness, which the Chymists are pleas’d to call, how properly I have elsewhere examin’d, the Sulphur of Vitriol. So that most part of Dissolv’d Bodyes being by Præcipitation brought to White Powders, and yet some affording Præcipitates of other Colours, the reason of both the Phænomena may deserve to be enquir’d into.