Experiment XVII
The emergency, Pyrophilus, of Colours upon the Coalition of the Particles of such Bodies as were neither of them of the Colour of that Mixture whereof they are the Ingredients, is very well worth our attentive Observation, as being of good use both Speculative and Practical; For much of the Mechanical use of Colours among Painters and Dyers, doth depend upon the Knowledge of what Colours may be produc’d by the Mixtures of Pigments so and so Colour’d. And (as we lately intimated) ’tis of advantage to the contemplative Naturalist, to know how many and which Colours are Primitive (if I may so call them) and Simple, because it both eases his Labour by confining his most sollicitous Enquiry to a small Number of Colours upon which the rest depend, and assists him to judge of the nature of particular compounded Colours, by shewing him from the Mixture of what more Simple ones, and of what Proportions of them to one another, the particular Colour to be consider’d does result. But because to insist on the Proportions, the Manner and the Effects of such Mixtures would oblige me to consider a greater part of the Painters Art and Dyers Trade, than I am well acquainted with, I confin’d my self to make Trial of several ways to produce Green, by the composition of Blew and Yellow. And shall in this place both Recapitulate most of the things I have Dispersedly deliver’d already concerning that Subject, and Recruit them.
And first, whereas Painters (as I noted above) are wont to make Green by tempering Blew and Yellow, both of them made into a soft Consistence, with either Water or Oyl, or some Liquor of Kin to one of those two, according as the Picture is to be Drawn with those they call water Colours, or those they term Oyl Colours, I found that by choosing fit Ingredients, and mixing them in the form of Dry Powders, I could do, what I could not if the Ingredients were temper’d up with a Liquor; But the Blew and Yellow Powders must not only be finely Ground, but such as that the Corpuscles of the one may not be too unequal to those of the other, lest by their Disproportionate Minuteness the Smaller cover and hide the Greater. We us’d with good success a slight Mixture of the fine Powder of Bise, with that of Orpiment, or that of good Yellow Oker, I say a slight Mixture, because we found that an exquisite Mixture did not do so well, but by lightly mingling the two Pigments in several little Parcels, those of them in which the Proportion and Manner of Mixture was more Lucky, afforded us a good Green.
2. We also learn’d in the Dye-houses, that Cloth being Dy’d Blew with Woad, is afterwards by the Yellow Decoction of Luteola or Woud-wax or Wood-wax Dy’d into a Green Colour.
3. You may also remember what we above Related, where we intimated, that having in a Darkn’d Room taken two Bodies, a Blew and a Yellow, and cast the Light Reflected from the one upon the other, we likewise obtain’d a Green.
4. And you may remember, that we observ’d a Green to be produc’d, when in the same Darkn’d Room we look’d at the Hole at which alone the Light enter’d, through the Green and Yellow parts of a sheet of Marbl’d Paper laid over one another.
5. We found too, that the Beams of the Sun being trajected through two pieces of Glass, the one Blew and the other Yellow, laid over one another, did upon a sheet of White paper on which they were made to fall, exhibit a lovely Green.
6. I hope also, that you have not already forgot, what was so lately deliver’d, concerning the composition of a Green, with a Blew and Yellow; of which most Authors would call the one a Real, and the other an Emphatical.
7. And I presume, you may have yet fresh in your memory, what the fourteenth Experiment informs you, concerning the exhibiting of a Green, by the help of a Blew and Yellow, that were both of them Emphatical.
8. Wherefore we will proceed to take notice, that we also devis’d a way of trying whether or no Metalline Solutions though one of them at least had its Colour Adventitious, by the mixture of the Menstruum employ’d to dissolve it, might not be made to compound a Green after the manner of other Bodies. And though this seem’d not easie to be perform’d by reason of the Difficulty of finding Metalline Solutions of the Colour requisite, that would mix without Præcipitating each other; yet after a while having consider’d the matter, the first Tryal afforded me the following Experiment. I took a High Yellow Solution of good Gold in Aqua-Regis, (made of Aqua-fortis, and as I remember half its weight of Spirit of Salt) To this I put a due Proportion of a deep and lovely Blew Solution of Crude Copper, (which I have elsewhere taught to be readily Dissoluble in strong Spirit of Urine) and these two Liquors though at first they seem’d a little to Curdle one another, yet being throughly mingl’d by Shaking, they presently, as had been Conjectur’d, united into a Transparent Green Liquor, which continu’d so for divers days that I kept it in a small Glass wherein ’twas made, only letting fall a little Blackish Powder to the Bottom. The other Phænomena of this Experiment belong not to this place, where it may suffice to take notice of the Production of a Green, and that the Experiment was more than once repeated with Success.
9. And lastly, to try whether this way of compounding Colours would hold ev’n in Ingredients actually melted by the Violence of the Fire, provided their Texture were capable of safely induring Fusion, we caus’d some Blew and Yellow Ammel to be long and well wrought together in the Flame of a Lamp, which being Strongly and Incessantly blown on them kept them in some degree of Fusion, and at length (for the Experiment requires some Patience as well as Skil) we obtain’d the expected Ammel of a Green Colour.
I know not, Pyrophilus, whether it be worth while to acquaint you with the ways that came into my Thoughts, whereby in some measure to explicate the first of the mention’d ways of making a Green; for I have sometimes Conjectur’d, that the mixture of the Bise and the Orpiment produc’d a Green by so altering the Superficial Asperity, which each of those Ingredients had apart, that the Light Incident on the mixture was Reflected with differing Shades, as to Quantity, or Order, or both, from those of either of the Ingredients, and such as the Light is wont to be Modify’d with, when it Reflects from Grass, or Leaves, or some of those other Bodies that we are wont to call Green. And sometimes too I have doubted, whether the produced Green might not be partly at least deriv’d from this, That the Beams that Rebound from the Corpuscles of the Orpiment, giving one kind of stroak upon the Retina, whose Perception we call Yellow, and the Beams Reflected from the Corpuscles of the Bise, giving another stroak upon the same Retina, like to Objects that are Blew, the Contiguity and Minuteness of these Corpuscles may make the Appulse of the Reflected Light fall upon the Retina within so narrow a Compass, that the part they Beat upon being but as it were a Physical point, they may give a Compounded stroak, which may consequently exhibit a Compounded and new Kind of Sensation, as we see that two Strings of a Musical Instrument being struck together, making two Noises that arrive at the Ear at the same time as to Sense, yield a Sound differing from either of them, and as it were Compounded of both; Insomuch that if they be Discordantly ton’d, though each of them struck apart would yield a Pleasing Sound, yet being struck together they make but a Harsh and troublesome Noise. But this not being so fit a place to prosecute Speculations, I shall not insist, neither upon these Conjectures nor any others, which the Experiment we have been mentioning may have suggested to me. And I shall leave it to you, Pyrophilus, to derive what Instruction you can from comparing together the Various ways whereby a Yellow and a Blew can be made to Compound a Green. That which I now pretend to, being only to shew that the first of those mention’d ways, (not to take at present notice of the rest) does far better agree with our Conjectures about Colours, than either with the Doctrine of the Schools, or with that of the Chymists, both which seem to be very much Disfavour’d by it.
For first, since in the Mixture of the two mention’d Powders I could by the help of a very excellent Microscope (for ordinary ones will scarce serve the turn) discover that which seem’d to the naked Eye a Green Body, to be but a heap of Distinct, though very small Grains of Yellow Orpiment and Blew Bise confusedly enough Blended together, it appears that the Colour’d Corpuscles of either kind did each retain its own Nature and Colour; By which it may be guess’d, what meer Transposition and Juxtaposition of Minute and Singly unchang’d Particles of Matter can do to produce a new Colour; For that this Local Motion and new Disposition of the small parts of the Orpiment did Intervene is much more manifest than it is easie to Explicate how they should produce this new Green otherwise than by the new Manner of their being put together, and consequently by their new Disposition to Modifie the Incident Light by Reflecting it otherwise than they did before they were Mingl’d together.
Secondly, The Green thus made being (if I may so speak) Mechanically produc’d, there is no pretence to derive it from I know not what incomprehensible Substantial Form, from which yet many would have us believe that Colours must flow; Nor does this Green, though a Real and Permanent, not a Phantastical and Vanid Colour, seem to be such an Inherent Quality as they would have it, since not only each part of the Mixture remains unalter’d in Colour, and consequently of a differing Colour from the Heap they Compose, but if the Eye be assisted by a Microscope to discern things better and more distinctly than before it could, it sees not a Green Body, but a Heap of Blew and Yellow Corpuscles.
And in the third place, I demand what either Sulphur, or Salt, or Mercury has to do in the Production of this Green; For neither the Bise nor the Orpiment were indu’d with that Colour before, and the bare Juxtaposition of the Corpuscles of the two Powders that work not upon each other, but might if we had convenient Instruments be separated, unalter’d, cannot with any probability be imagin’d either to Increase or Diminish any of the three Hypostatical Principles, (to which of them soever the Chymists are pleas’d to ascribe Colours) nor does there here Intervene so much as Heat to afford them any colour to pretend, that at least there is made an Extraversion (as the Helmontians speak) of the Sulphur or of any of the two other supposed Principles; But upon this Experiment we have already Reflected enough, if not more than enough for once.