Experiment X.
We have ſometimes found in the Shops of our Druggiſts, a certain Wood, which is there called Lignum Nephriticum, becauſe the Inhabitants of the Country where it grows, are wont to uſe the Infuſion of it made in fair Water againſt the Stone of the Kidneys, and indeed an Eminent Phyſician of our Acquaintance, who has very Particularly enquir’d into that Diſeaſe, aſſures me, that he has found ſuch an Infuſion one of the moſt effectual Remedyes, which he has ever tried againſt that formidable Diſeaſe. The ancienteſt Account I have met with of this Simple, is given us by the Experienc’d Monardes in theſe Words. Nobis, ſays he,16 Nova Hiſpania mittit quoddam ligni genus craſſum & enode, cujus uſus jam diu receptus fuit in his Regionibus ad Renum vitia & urinæ difficultates ac arenulas pellendas. Fit autem hac ratione, Lignum aſſulatim & minutim conciſum in limpidiſſima aqua fontana maceratur, inque ea relinquitur, donec aqua à bibentibus abſumpta ſit, dimidia hora post injectum lignum aqua cæruleum colorem contrabit, qui ſenſim intenditur pro temporis diuturnitate, tametſi lignum candidum fit. This Wood, Pyrophilus, may afford us an Experiment, which beſides the ſingularity of it, may give no ſmall aſſiſtance to an attentive Conſiderer towards the detection of the Nature of Colours. The Experiment as we made it is this. Take Lignum Nephriticum, and with a Knife cut it into thin Slices, put about a handfull of theſe Slices into two three or four pound of the pureſt Spring-water, let them infuſe there a night, but if you be in haſt, a much ſhorter time may ſuffice; decant this Impregnated Water into a clear Glaſs Vial, and if you hold it directly between the Light and your Eye, you ſhall ſee it wholly Tincted (excepting the very top of the Liquor, wherein you will ſome times diſcern a Sky-colour’d Circle) with an almoſt Golden Colour, unleſs your Infuſion have been made too Strong of the Wood, for in that caſe it will againſt the Light appear ſomewhat Dark and Reddiſh, and requires to be diluted by the addition of a convenient quantity of fair Water. But if you hold this Vial from the Light, ſo that your Eye be plac’d betwixt the Window and the Vial, the Liquor will appear of a deep and lovely Cæruleous Colour, of which alſo the drops, if any be lying on the outſide of the Glaſs, will ſeem to be very perfectly; And thus far we have try’d the Experiment, and found it to Succeed even by the Light of Candles of the larger ſize. If you ſo hold the Vial over againſt your Eyes, that it may have a Window on one ſide of it, and a Dark part of the Room both before it and on the other ſide, you ſhall ſee the Liquor partly of a Blewiſh and partly of a Golden Colour. If turning your back to the Window, you powr out ſome of the Liquor towards the Light and towards your Eyes, it will ſeem at the comming out of the Glaſs to be perfectly Cæruleous, but when it is fallen down a little way, the drops may ſeem Particolour’d, according as the Beams of Light do more or leſs fully Penetrate and Illuſtrate them. If you take a Baſon about half full of Water, and having plac’d it ſo in the Sun-beams Shining into a Room, that one part of the Water may be freely illuſtrated by the Beams of Light, and the other part of it Darkned by the ſhadow of the Brim of the Baſon, if then I ſay you drop of our Tincture, made ſomewhat ſtrong, both into the Shaded and Illuminated parts of the Water, you may by looking upon it from ſeveral places, and by a little Agitation of the water, obſerve divers pleaſing Phænomena which were tedious to particularize. If you powr a little of this Tincture upon a ſheet of White Paper, ſo as the Liquor may remain of ſome depth upon it, you may perceive the Neighbouring drops to be partly of one Colour, and partly of the other, according to the poſition of your Eye in reference to the Light when it looks upon them, but if you powr off all the Liquor, the Paper will ſeem Dy’d of an almoſt Yellow Colour. And if a ſheet of Paper with ſome of this Liquor in it be plac’d in a window where the Sunbeams may ſhine freely on it, then if you turn your back to the Sun and take a Pen or ſome ſuch ſlender Body, and hold it over-thwart betwixt the Sun and the Liquor, you may perceive that the Shadow projected by the Pen upon the Liquor, will not all of it be a vulgar and Dark, but in part a curiouſly Colour’d ſhadow, that edge of it, which is next the Body that makes it, being almoſt of a lively Golden Colour, and the remoter verge of a Cæruleous one.
Theſe and other Phænomena, which I have obſerv’d in this delightfull Experiment, divers of my friends have look’d upon not without ſome wonder, and I remember an excellent Oculiſt finding by accident in a friends Chamber a fine Vial full of this Liquor, which I had given that friend, and having never heard any thing of the Experiment, nor having any Body near him that could tell him what this ſtrange Liquor might be, was a great while apprehenſive, as he preſently after told me, that ſome ſtrange new diſtemper was invading his Eyes. And I confeſs that the unuſualneſs of the Phænomena made me very ſollicitous to find out the Cauſe of this Experiment, and though I am far from pretending to have found it, yet my enquiries have, I ſuppoſe, enabled me to give ſuch hints, as may lead your greater ſagacity to the diſcovery of the Cauſe of this wonder. And firſt finding that this Tincture, if it were too copious in the water, Kept the Colours from being ſo lively, and their Change from being ſo diſcernable, and finding alſo that the Impregnating Virtue of this Wood did by its being frequently Infus’d in New Water by degrees Decay, I Conjectur’d that the Tincture afforded by the Wood muſt proceed from ſome Subtiler parts of it drawn forth by the Water, which ſwimming too and fro in it did ſo Modifie the Light, as to exhibit ſuch and ſuch Colours; and becauſe theſe Subtile parts were ſo eaſily Soluble even in Cold water, I concluded that they muſt abound with Salts, and perhaps contain much of the Eſſential Salt, as the Chymiſts call it, of the Wood. And to try whether theſe Subtile parts were Volatile enough to be Diſtill’d, without the Diſſolution of their Texture, I carefully Diſtill’d ſome of the Tincted Liquor in very low Veſſels, and the gentle heat of a Lamp Furnace; but found all that came over to be as Limpid and Colourleſs as Rock-water, and the Liquor remaining in the Veſſel to be ſo deeply Cæruleous, that it requir’d to be oppos’d to a very ſtrong Light to appear of any other Colour. I took likewiſe a Vial with Spirit of Wine, and a little Salt of Harts-horn, and found that there was a certain proportion to be met with betwixt the Liquor and the Salt, which made the Mixture fit to exhibit ſome little Variety of Colours not Obſervable in ordinary Liquors, as it was variouſly directed in reference to the Light and the Eye, but this Change of Colour was very far ſhort from that which we had admir’d in our Tincture. But however, I ſuſpected that the Tinging Particles did abound with ſuch Salts, whoſe Texture, and the Colour ſpringing from it, would probably be alter’d by peircing Acid Salts, which would in likelihood either make ſome Diſſipation of their Parts, or Aſſociate themſelves to the like Bodies, and either way alter the Colour exhibited by them; whereupon Pouring into a ſmall Vial full of Impregnated Water, a very little Spirit of Vinegar, I found that according to my Expectation, the Cæruleous Colour immediately vaniſh’d, but was deceiv’d in the Expectation I had, that the Golden Colour would do ſo too; for, which way ſoever I turned the Vial, either to or from the Light, I found the Liquor to appear always of a Yellowiſh Colour and no other: Upon this I imagin’d that the Acid Salts of the Vinegar having been able to deprive the Liquor of its Cæruleous Colour, a Sulphureous Salt being of a contrary Nature, would be able to Mortifie the Saline Particles of Vinegar, and Deſtroy their Effects; And accordingly having plac’d my Self betwixt the Window, and the Vial, and into the Same Liquor dropt a few drops of Oyl of Tartar per Deliquium, (as Chymiſts call it) I obſerv’d with pleaſure, that immediately upon the Diffuſion of this Liquor, the Impregnated Water was reſtor’d to its former Cæruleous Colour; And this Liquor of Tartar being very Ponderous, and falling at firſt to the Bottom of the Vial, it was eaſie to obſerve that for a little while the Lower part of the Liquor appear’d deeply Cæruleous; whilſt all the Upper part retain’d its former Yellowneſs, which it immediately loſt as ſoon as either Agitation or Time had made a competent Diffuſion of the Liquor of Tartar through the Body of the former Tincture; and this reſtored Liquor did, as it was Look’d upon againſt or from the Light, exhibit the Same Phænomena as the Tincted Water did, before either of the Adventitious Liquors was pour’d into it.
Having made, Pyrophilus, divers Tryals upon this Nephritick Wood, we found mention made of it by the Induſtrious Jeſuit Kircherus, who having received a Cup Turned of it from the Mexican Procurator of his Society, has probably receiv’d alſo from him the Information he gives us concerning that Exotick Plant, and therefore partly for that Reaſon, and partly becauſe what he Writes concerning it, does not perfectly agree with what we have deliver’d, we ſhall not Scruple to acquaint you in his own Words, with as much of what he writes concerning our Wood, as is requiſite to our preſent purpoſe. Hoc loco (ſays he)17 neutiquam omittendum duximus quoddam ligni candidi Mexicani genus, quod Indigenæ Coalle & Tlapazatli vocant, quod etſi experientia hucuſque non niſi Cæruleo aquam colore tingere docuerit, nos tamen continua experientia invenimus id aquam in omne Colorum genus transformare, quod merito cuipiam Paradoxum videri poſſet; Ligni frutex grandis, ut aiunt, non rarò in molem arboris excreſcit, truncus illius eft craſſus, enodis, inſtar piri arboris, folia ciceris foliis, aut rutæ haud abſimilia, flores exigui, oblongi, lutei & ſpicatim digeſti; eſt frigida & humida planta, licet parum recedat à medio temperamento. Hujus itaque deſcriptæ arboris lignum in poculum efformatum, aquam eidem infuſam primo in aquam intenſe Cæruleam, colore floris Bugloſſæ; tingit, & quo diutius in eo ſteterit, tanto intenſiorem colorem acquirit. Hanc igitur aquam si Vitreæ Sphæræ infuderis, lucique expoſueris, ne ullum quidem Cærulei coloris veſtigium apparebit, ſed inſtar aquæ puræ putæ fontanæ limpidam claramque aspicientibus ſe præbebit. Porro ſi hanc phialam vitream verſus locum magis umbroſum direxeris, totus humor gratiſſimum virorem referet; ſi adhuc umbroſioribus locis, ſubrubrum, & ſic pro rerum objectarum conditione, mirum dictu, colorem mutabit; in tenebris verò vel in vaſe opaco poſita, Cæruleum colorem ſuum reſumet.
In this paſſage we may take notice of the following Particulars. And firſt, he calls it a White Mexican Wood, whereas (not to mention that Mornardes informs us that it is brought out of Nova Hiſpania) the Wood that we have met with in ſeveral places, and employ’d as Lignum Nephriticum, was not White, but for the moſt part of a much Darker Colour, not unlike that of the Sadder Colour’d Wood of Juniper. ’Tis true, that Monardes himſelf alſo ſays, that the Wood is White; and it is affirm’d, that the Wood which is of a Sadder Colour is Adulterated by being Imbu’d with the Tincture of a Vegetable, in whoſe Decoction it is ſteep’d. But having purpoſely enquir’d of the Eminenteſt of our Engliſh Druggiſts, he peremptorily deny’d it. And indeed, having conſider’d ſome of the faireſt Round pieces of this Wood that I could meet with in theſe Parts, I had Opportunity to take notice that in one or two of them it was the External part of the Wood that was White, and the more Inward part that was of the other Colour, the contrary of which would probably have appear’d, if the Wood had been Adulterated after the afore-mention’d manner. And I have at preſent by me a piece of ſuch Wood, which for about an Inch next the Bark is White, and then as it were abruptly paſſes to the above-mention’d Colour, and yet this Wood by the Tincture, it afforded us in Water, appears to have its Colour’d part Genuine enough; for as for the White part, it appears upon tryal of both at once, much leſs enrich’d with the tingent Property.
Next, whereas our Author tells us, that the Infuſion of this Wood expos’d in a Vial to the Light, looks like Spring-water, in which he afterwards adds, that there is no Tincture to be ſeen in it, our Obſervation and his agree not, for the Liquor, which oppoſed to the Darker part of a Room exhibits a Sky-colour, did conſtantly, when held againſt the Light, appear Yellowiſh or Reddiſh, according as its Tincture was more Dilute or Deep; and then, whereas it has been already ſaid, that the Cæruleous Colour was by Acid Salts aboliſhed, this Yellowiſh one ſurviv’d without any conſiderable Alteration, ſo that unleſs our Author’s Words be taken in a very Limited Senſe, we muſt conclude, that either his Memory mis-inform’d him, or that his White Nephritick Wood, and the Sadder Colour’d one which we employ’d, were not altogether of the ſame Nature: What he mentions of the Cup made of Lignum Nephriticum, we have not had Opportunity to try, not having been able to procure pieces of that Wood great enough, and otherwiſe fit to be turned into Cups; but as for what he ſays in the Title of his Experiment, that this Wood tinges the Water with all Sorts of Colours, that is much more than any of thoſe pieces of Nephritick Wood that we have hitherto employ’d, was able to make good; The change of Colours diſcernable in a Vial full of Water, Impregnated by any of them, as it is directed towards a place more Lightſome or Obſcure, being far from affording a Variety anſwerable to ſo promiſing a Title. And as for what he tells us, that in the Dark the Infuſion of our Wood will reſume a Cæruleous Colour, I wiſh he had Inform’d us how he Try’d it.
But this brings into my mind, that having ſometimes for Curioſity ſake, brought a round Vial with a long Neck fill’d with the Tincture of Lignum Nephriticum into the Darken’d Room already often mention’d, and holding it ſometimes in, ſometimes near the Sun-beams that enter’d at the hole, and ſometimes partly in them, and partly out of them, the Glaſs being held in ſeveral poſtures, and look’d upon from ſeveral Neighbouring parts of the Room, diſclos’d a much greater Variety of Colours than in ordinary inlightn’d Rooms it is wont to do; exhibiting, beſides the uſual Colours, a Red in ſome parts, and a Green in others, beſides Intermediate Colours produc’d by the differing Degrees, and odd mixtures of Light and Shade.
By all this You may ſee, Pyrophilus, the reaſonableneſs of what we elſewhere had occaſion to mention, when we have divers times told you, that it is uſefull to have New Experiments try’d over again, though they were, at firſt, made by Knowing and Candid Men, ſuch Reiterations of Experiments commonly exhibiting ſome New Phænomena, detecting ſome Miſtake or hinting ſome Truth, in reference to them, that was not formerly taken notice of. And ſome of our friends have been pleas’d to think, that we have made no unuſefull addition to this Experiment, by ſhewing a way, how in a moment our Liquor may be depriv’d of its Blewneſs, and reſtor’d to it again by the affuſion of a very few drops of Liquors, which have neither of them any Colour at all of their own. And that which deſerves ſome particular wonder, is, that the Cæruleous Tincture of our Wood is ſubject by the former Method to be Deſtroy’d or Reſtor’d, the Yellowiſh or Reddiſh Tincture continuing what it was. And that you may ſee, that Salts are of a conſiderable uſe in the ſtriking of Colours, let me add to the many Experiments which may be afforded us to this purpoſe by the Dyers Trade, this Obſervation; That as far as we have hitherto try’d, thoſe Liquors in general that are ſtrong of Acid Salts have the Power of Deſtroying the Blewneſs of the Infuſion of our Wood, and thoſe Liquors indiſcriminatly that abound with Sulphureous Salts, (under which I comprehend the Urinous and Volatile Salts of Animal Subſtances, and the Alcaliſate or fixed Salts that are made by Incineration) have the vertue of Reſtoring it.
A Corollary of the Tenth Experiment.
That this Experiment, Pyrophilus, may be as well Uſefull as Delightfull to You, I muſt mind You, Pyrophilus, that in the newly mention’d Obſervation, I have hinted to You a New and Eaſie way of Diſcovering in many Liquors (for I dare not ſay in all) whether it be an Acid or Sulphureous Salt, that is Predominant; and that ſuch a Diſcovery is oftentimes of great Difficulty, and may frequently be of great Uſe, he that is not a Stranger to the various Properties and Effects of Salts, and of how great moment it is to be able to diſtinguiſh their Tribes, may readily conceive. But to proceed to the way of trying other Liquors by an Infuſion of our Wood, take it briefly thus. Suppoſe I have a mind to try whether I conjecture aright, when I imagine that Allom, though it be plainly a Mixt Body, does abound rather with Acid than Sulphureous Salt. To ſatisfie my ſelf herein, I turn my back to the Light, and holding a ſmall Vial full of the Tincture of Lignum Nephriticum, which look’d upon in that Poſition, appears Cæruleous, I drop into it a little of a ſtrong Solution of Allom made in Fair Water, and finding upon the Affuſion and ſhaking of this New liquor, that the Blewneſs formerly conſpicuous in our Tincture does preſently vaniſh, I am thereby incited to ſuppoſe, that the Salt Prædominant in Allom belongs to the Family of Sour Salts; but if on the other ſide I have a mind to examine whether or no I rightly conceive that Salt of Urine, or of Harts-horn is rather of a Saline Sulphureous (if I may ſo ſpeak) than of an Acid Nature, I drop a little of the Saline Spirit of either into the Nephritick Tincture, and finding that the Cæruleous Colour is rather thereby Deepned than Deſtroy’d, I collect that the Salts, which conſtitute theſe Spirits, are rather Sulphureous than Acid. And to ſatisfie my ſelf yet farther in this particular, I take a ſmall Vial of freſh Tincture, and placing both it and my ſelf in reference to the Light as formerly, I drop into the Infuſion juſt as much Diſtill’d Vinegar, or other Acid liquor as will ſerve to Deprive it of its Blewneſs (which a few drops, if the Sour Liquor be ſtrong, and the Vial ſmall will ſuffice to do) then without changing my Poſture, I drop and ſhake into the ſame Vial a ſmall proportion of Spirit of Hartſhorn or Urine, and finding that upon this affuſion, the Tincture immediately recovers its Cæruleous Colour, I am thereby confirm’d firm’d in my former Opinion, of the Sulphureous Nature of theſe Salts. And ſo, whereas it is much doubted by Some Modern Chymiſts to what ſort of Salt, that which is Prædominant in Quick-lime belongs, we have been perſwaded to referr it rather to Lixiviate than Acid Salts, by having obſerv’d, that though an Evaporated Infuſion of it will ſcarce yield ſuch a Salt, as Aſhes and other Alcalizate Bodyes are wont to do, yet if we deprive our Nephritick Tincture of its Blewneſs by juſt ſo much Diſtill’d Vinegar as is requiſite to make that Colour Vaniſh, the Lixivium of Quick-lime will immediately upon its Affuſion recall the Baniſhed Colour; but not ſo Powerfully as either of the Sulphureous Liquors formerly mention’d. And therefore I allow my ſelf to gueſs at the Strength of the Liquors examin’d by this Experiment, by the Quantity of them which is ſufficient to Deſtroy or Reſtore the Cæruleous Colour of our Tincture. But whether concerning Liquors, wherein neither Acid nor Alcaliſate Salts are Eminently Prædominant, our Tincture will enable us to conjecture any thing more than that ſuch Salts are not Prædominant in them, I take not upon me to determine here, but leave to further Tryal; For I find not that Spirit of Wine, Spirit of Tartar freed from Acidity, or Chymical Oyl of Turpentine, (although Liquors which muſt be conceiv’d very Saline, if Chymiſts have, which is here no place to Diſpute, rightly aſcrib’d taſts to the Saline Principle of Bodyes,) have any Remarkable Power either to deprive our Tincture of its Cæruleous Colour, or reſtore it, when upon the Affuſion of Spirit of Vinegar it has diſappear’d.