§ 3 The Internal Activity of Bodies
Migration of Material Particles.—In the Brownian movement we take into account only very small, isolated masses, small free fragments—i.e., material particles which are not hampered by their relations to neighbouring particles. Any one but a physicist might believe that in true solids endowed with cohesion and tenacity, in which the molecules were bound one to the other, in which form and volume are fixed, there could be no longer movements or changes. This is a mistake. Physics teaches us the contrary, and, in late years especially, has furnished us characteristic examples. There are real migrations of material particles throughout solid bodies—migrations of considerable extent. They are accomplished through the agency of diverse forces acting externally—pressures, thrusts, torsions; sometimes under the action of light, sometimes under the action of electricity, sometimes under the influence of forces of diffusion. The microscopic observation of alloys by H. and A. Lechatelier, J. Hopkinson, Osmond, Charpy, J. R. Benoit; researches into their physical and chemical properties by Calvert, Matthiessen, Riche, Roberts Austen, Lodge, Laurie, and C. E. Guillaume; experiments on the electrolysis of glass, and the curious results of Bose upon electrical contact of metals, show in a striking manner the chemical and kinetic evolutions which occur in the interior of bodies.
Migration under the Action of Weight.—An experiment by Obermeyer, dating from 1877, furnishes a good example of the motions of solid bodies through a hardened viscid mass, taking place under the influence of weight. The black wax that shoemakers and boatbuilders use, is a kind of resin extracted from the pine and other resinous trees, melted in water, and separated from the more fluid part which rises from it. Its colour is due to the lampblack produced by the combustion of straw and fragments of bark. At an ordinary temperature it is a mass so hard that it cannot always be easily scratched by the finger-nail; but if it is left to itself in a receptacle, it finally yields, spreads out as if it were a liquid, and conforms to the shape of the vessel. Suppose we place within a cavity hollowed out of a piece of wood a portion of this substance, and keep it there by means of a few pebbles, having previously placed at the bottom of the cavity a few fragments of some light substance, such as cork. The piece of wax is thus between a light body below and a heavy body above. If we wait a few days, this order is reversed—the wax has filled the cavity by conforming to it; the cork has passed through the wax and appears on the surface, while the stones are at the bottom. We have here the celebrated experiment of the flask with the three elements, in which are seen the liquids mercury, oil, and water superposed in the order of their density, but in this case demonstrated with solid bodies.
Influence of Diffusion.—Diffusion, which disseminates liquids throughout each other, may also cause solids to pass through other solids. Of this W. Roberts Austen gave a convincing proof. This ingenious physicist placed a little cylinder of lead upon a disc of gold, and kept the whole at the temperature of boiling water. At this temperature both metals are perfectly solid, for the melting point of gold is 1,200° C., and of lead is 330°. Still, after this contact has been prolonged for a month and a half, analysis shows that the gold has become diffused through the top of the cylinder of lead.
Influence of Electrolysis.—Electrolysis offers another no less remarkable means of transportation. By its means we may force metals, such as sodium or lithium, through glass walls. The experiment may be performed as indicated by M. Charles Guillaume. A glass bulb containing mercury is placed in a bath of sodium amalgam, and a current is then made to pass from within outward. After some time it can be shown that the metal has penetrated the wall of the bulb, and has become dissolved within it.
Influence of Mechanical Pressure.—Mechanical pressure is also capable of causing one metal to pass into another. We need not recall the well-known experiment of Cailletet, who, by employing considerable pressure, caused mercury to sweat through a block of iron. In a more simple manner W. Spring showed that a disc of copper could be welded to a disc of tin by pressing them strongly one against the other. Up to a certain distance from the surfaces of contact a real alloy is formed; a layer of bronze of a certain thickness unites the two metals, and this could not take place did not the particles of both metals mutually interpenetrate.