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A Manual of Photographic Chemistry

by T. Frederick Hardwich

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Nitrate of Baryta

Symbol, BaO NO5. Atomic weight, 131.

Nitrate of Baryta forms octahedral crystals, which are anhydrous. It is considerably less soluble than the Chloride of Barium, requiring 12 parts of cold and 4 of boiling water for solution. It may be substituted for the Nitrate of Lead in the preparation of Protonitrate of Iron.

NITRATE OF LEAD.

Symbol, PbO NO5. Atomic weight, 166.

Nitrate of Lead is obtained by dissolving the metal, or the Oxide of Lead, in excess of Nitric Acid, diluted with 2 parts of water. It crystallizes on evaporation in white anhydrous tetrahedra and octahedra, which are hard, and decrepitate on being heated; they are soluble in 8 parts of water at 60°.

Nitrate of Lead forms with Sulphuric Acid, or soluble Sulphates, a white precipitate, which is the insoluble Sulphate of Lead. The Iodide of Lead is also very sparingly soluble in water.

NITRATE OF SILVER, See Silver, Nitrate or.

NITRO-GLUCOSE.

When 3 fluid ounces of cold Nitro-Sulphuric Acid, consisting of 2 ounces of Oil of Vitriol and 1 ounce of highly concentrated Nitric Acid, are mixed with 1 ounce of finely powdered Cane Sugar, there is formed at first a thin, transparent, pasty mass. If it is stirred with a glass rod for a few minutes without interruption, the paste coagulates as it were, and separates from the liquid as a thick tenacious mass, aggregating into lumps, which can easily be removed from the acid mixture.

This substance has a very acid and intensely bitter taste. Kneaded in warm water until the latter no longer reddens litmus-paper, it acquires a silver colour and a beautiful silky lustre. It may be used in Photography to confer intensity upon newly mixed Collodion; but is inferior to Glycyrrhizine employed for the same purpose.

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